PostgreSQL 9.3 will be coming out in beta soon and with that, some who want to experiment with both PostGIS and PostgreSQL 9.3 have asked if they can use PostGIS 2.0. The answer is NO. A lot of major changes happened in PostgreSQL 9.3 that required us to patch up upcoming PostGIS 2.1. These changes were not backported to 2.0 and I personally do not plan to back-port them unless lightning strikes me and I escape unscathed, a big wad of cash falls from the sky, or for some reason we can't make the 2.1 cut before 9.3 comes out. So if you are planning to experiment with PostgreSQL 9.3, PLEASE use PostGIS 2.1 development branch. I will try to make sure we release 2.1 before PostgreSQL 9.3 comes out even if I have to resort to hitting some people over the head with a rubber bat :).
If ever in doubt what versions of PostGIS works with what versions of PostgreSQL /GEOS / GDAL, please refer to the matrix that we try to keep up to date. http://trac.osgeo.org/postgis/wiki/UsersWikiPostgreSQLPostGIS.
Now some people might say "Isn't it cruel not to support PostGIS 2.0 for 9.3", and my answer is "it's crueler to". The reason is simple. We have limited bandwidth for testing permutations of things and the more permutations of things we support, the dirtier our code base becomes making it harder to maintain and also the less time we can devote to properly testing each permutation. I'd rather say we don't support something than to do a half-hearted job of supporting all. On a slightly different, but also pragmatic note, package maintainers (except for windows maintainers :)) generally only carry one version of PostGIS per version of PostgreSQL, and I'd rather users getting from packages see our best foot than a two year old aging foot.
Note: that going from PostGIS 2.0 to 2.1 is a soft upgrade so you can install 2.1 on your existing PostgreSQL 9.2 without dump restore and then you should be able to pg_upgrade over to 9.3 if your database is too big to dump restore.